赵金安,男,中共党员,教授,理学博士,郑州大学化学与分子工程学院硕士生导师。
1983.9—1987.7郑州大学化学系理学学士
2001.9—2004.9郑州大学化学系无机化学专业理学硕士
2005.9—2009.6郑州大学化学系无机化学专业理学博士
教学工作方面,主要从事《普通化学》、《无机化学》、《分析化学》和《无机及分析化学》等课程的讲授。出版了《无机及分析化学》、《无机及分析化学实验》等教材4部。
科研工作方面,主要从事生物无机化学功能配合物化学纳米复合材料的研究。近年来,在J. Am. Chem. Soc., Chem. Commun., New J. Chem., J. Inorg. Biochem.等期刊公开发表SCI学术论文近30篇,主持完成国家自然科学基金面上项目一项、省部级重点科技攻关项目多项,以第二参与单位主持国家973基础科学研究项目子课题1项,以第一发明人授权国家发明专利6项。
以第一完成人授权国家发明专利:
1.一种乙烯-醋酸乙烯酯共聚物/聚苯胺复合导电材料及其制备方法/发明专利,专利号:ZL201410666663.7/2241550,授权公告号:CN104448303B。
2.一种乙烯-醋酸乙烯酯共聚物/聚吡咯复合导电材料及其制备方法/发明专利,专利号:ZL201410666739.6/2250746,授权公告号:CN104479211B。
3.一种等离子辅助预处理制备玻璃导电纤维的方法/发明专利,专利号:ZL201610209924.1/2740167,授权公告号:CN105800964B。
4.一种以硫化亚铜为导电层的玻璃导电纤维的制备方法,专利号:2016102099256,授权公告号:CN105800963B。
5.一种聚丙烯腈电磁屏蔽纳米复合材料的制备方法,申请号:2012105220954,授权公告号:CN103160053B。
6.一种纳米银/碳纳米管/聚乙烯醇复合导电薄膜的制备方法,申请号:2012105223755,授权公告号:CN103160049B。
主持完成的各级科研项目:
1.《基于抗肿瘤活性的多核配合物设计、合成及作用研究》,国家自然科学基金(21371046),主持人,资助经费:90.0万元。
2.《中心金属及空间构型调控的金属-有机杂化材料催化性能研究》,河南省重点科技攻关项目(132102310121),项目主持人。
3.《金属大环基聚合物的构筑、性能研究及应用》,河南省重点科技攻关项目(112102310084),项目主持人。
4.《药物配体构筑的金属配合物的抗肿瘤活性研究》河南省高校创新人才支持计划项目(2010HASTIT016),项目主持人。
5.《秸秆类生物质微生物高效转化的基础研究》国家重点基础研究发展计划(973计划)2006CB708407-2第二主持人。
6.《超细氧化铝粉体制备新工艺》河南省科技厅项目,项目主持人。
7.《冰箱专用二氧化钛杀菌钢化玻璃制备工艺》河南省科技厅项目,项目主持人。
8.《高纯超细莫来石粉体化学法制备工艺》河南省科技厅项目,主要完成人。
9.《聚合物共混纺丝法制备纳米碳纤维及其作为吸波材料的应用》河南省科技厅项目,主要完成人。
10.《二茂铁酸类配体构筑的多聚配合物研究》,河南自然科学基金(611021800 ),项目主持人。
近年来代表性论文:
1.Jin’an Zhao, Liwei Mi, Jiyong Hu, Hongwei Hou*, Yaoting Fan, Cation Exchange Induced Tunable Properties of a Nanoporous Octanuclear Cu(II) Wheel with Double-Helical Structure,J. Am. Chem. Soc., 2008, 130(46), 15222–15223.
2. Junshuai Zhang, Jiyong Hu, Kun Peng, Wei Song, Shuangcheng Zhi, Endian Yang,Jin’an Zhao*and Hongwei Hou, Chemical biology suggests pleiotropic effects for a novel hexanuclear copper(II) complex inducing apoptosis in hepatocellular carcinoma cells, Chem. Commun., 2019, 55, 11944–11947.
3. Shuangcheng Zhi, Yuyang Li, Jiaxu Qiang, Jiyong Hu, Wei Song,Jin'an Zhao*, Synthesis and anticancer evaluation of benzo-N-heterocycles transition metal complexes against esophageal cancer cell lines. Journal of inorganic biochemistry, 2019, 201, 110816.
4. Jiyong Hu, Shufang Chen, Ruina Mao, Chunli Liao, Hao Yang,Jin'an Zhao*, Cytotoxicity, dual-targeting apoptosis induction evaluation of multinuclear cu complexes based on pyrazine-benzimidazole derivative, Journal of Inorganic Biochemistry, 2018, 186, 246–256.
5. Jiyong Hu, Chunli Liao, Ruina Mao, Junshuai Zhang,Jin'an Zhao*and Zhenzhen Gu, DNA interactions andin vitro anticancer evaluations of pyridine-benzimidazole-based Cu complexes, Med. Chem. Commun., 2018, 9, 337–343.
6. Jiyong Hu, Yan Guo,Jin’an Zhao*, Junshuai Zhang, In vitro antitumor activity of novel benzimidazole-based Cu(II) complexes, Bioorganic & Medicinal Chemistry, 2017, 25, 5733–5742.
7. Jiyong Hu, Chunli Liao, Yan Guo, Fan Yang, Wei Sang,Jin’an Zhao*, Copper(II) complexes inducing apoptosis in cancer cells, and demonstrating DNA and HSA interactions, Polyhedron, 2017, 132, 28–38.
8.Jin’an Zhao*, Shuangcheng Zhi, Huaibin Yu, Jin Zhang, Junshuai Zhang and Jiyong Hu, Synthesis, crystal structure, DNA/BSA interaction and in vitro antitumor activity of N-heterocycle Cu(II) and Co(II) complexes, J. Coord. Chem., 2017, 70(18), 3110–3131.
9.Jin'an Zhao*, Shuangcheng Zhi, Huaibin Yu, Ruina Mao, Jiyong Hu, Wei Song and Junshuai Zhang, Mitochondrial and nuclear DNA dual damage induced by 2-(2ʹ-quinolyl)benzimidazole copper complexes with potential anticancer activity. RSC Adv., 2017,7, 51162–51174.
10.Jin-An Zhao*, Huai-Bin Yu, Shuang-Cheng Zhi, Rui-Na Mao, Ji-Yong Hu, Xiao-Xiao Wang, Synthesis, chemical nuclease activity, and in vitro cytotoxicity of benzimidazole- based Cu(II)/Co(II) complexes, Chin. Chem. Lett., 2017, 28, 1539–1546.
11. Shufang Chen, Jiyong Hu,Jin'an Zhao*, Jin Zhang, Huaibin Yu, Shuangcheng Zhi, Junshuai Zhang, Zhanqiang Gong, Two cyclohexane-type octadecanuclear metalla- macrocycle-based metal organic frameworks and adsorption properties, CrystEngComm., 2016, 18,5353–5359. 12.Jin’an Zhao*, Kun Peng, Yan Guo, Jin Zhang, Shufang Chen and Jiyong Hu, Photoluminescent and cytotoxic properties of multinuclear complexes and multinuclear-based polymers with group
12 metals and a tripodal ligand, New J. Chem., 2015, 39, 6016–6024.
13.Jin’an Zhao*, Yan Guo, Kun Peng, Jin Zhang, Chuangcheng Zhang, Liangliang Hu, Shufang Chen, Jiyong Hu, Anion directed Cu(I) complexes constructed from a benzotriazole derivative and their photoluminescence, Polyhedron, 2015, 85, 593–597.
14.Jin’an Zhao*, Dandan Zhao, Shufang Chen, Jin Zhang and Jiyong Hu, The tetrazole–carboxylate bifunctional ligand directed three structural diversity complexes, Inorg. Chim. Acta., 2015, 428, 112–116.
15.Jin’an Zhao*, Dandan Zhao, Yan Guo, Kun Peng, Xinling Li, Shufang Chen and Jiyong Hu, Photoluminescence properties of three d10complexes constructed from the bifunctional benzimidazole-carboxylate-based connector, Inorg. Chim. Acta., 2014, 418, 8–14.
16.JIN’AN ZHAO*, KUN PENG, YAN GUO, JIN ZHANG, DANDAN ZHAO, SHUFANG CHEN and JIYONG HU,Cytotoxicity towards human alimentary system carcinoma cells resulting from diverse copper(II) complexes, J. Coord. Chem., 2014, 67(13), 2344–2356.
17.Jin-An Zhao*, Shu-Fang Chen, Dan-Dan Zhao, Yan Guo, Kun Peng, Ji-Yong Hu, The structure and luminescence properties of three complexes based on bifunctional imidazole-dicarboxylate connector, Chin. Chem. Lett., 2013, 24, 483–486.
18.Jin’an Zhao*,Shenshen Li, Dandan Zhao, Shufang Chen, Jiyong Hu, Metal center and structure tunedin vitroantitumor activityof benzimidazole-basedcopperand zinc complexes, J. Coord. Chem., 2013,66(9), 1650–1660.
19.Jin’an Zhao*, Dandan Zhao, Yan Guo, Kun Peng, Shufang Chen, Jiyong Hu, Two Ag(I) complexes constructed from the flexible Tripodal pyridyl-benzimidazole-based connector, Synth. React. Inorg. M., 2013, 44(4), 523–529.
20.Jin’an Zhao*, Dandan Zhao, Kun Peng, Yan Guo, Shufang Chen, Jiyong Hu, The versatile coordination fashion of bifunctional benzimidazole-carboxylate connector directed three structural diversity complexes, Transition Met. Chem., 2013, 38(7), 771–777.
21.JIN’AN ZHAO*, JIYONG HU, YUN BAI, SHUFANG CHEN, SHENSHEN LI, Construction of three 2-D silver(I) coordination architectures with a flexible pyrazine-based ligand, J. Coord. Chem., 2012, 65(18), 3216–3226.
22.JIN’AN ZHAO*, SHENSHEN LI, SHUFANG CHEN, YUN BAI, JIYONG HU, Metallacycle-based complexes based on a flexible pyridyl–benzimidazole derivative, J. Coord. Chem., 2012, 65(7), 1201–1211. 。
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